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1.
Environ Sci Pollut Res Int ; 30(54): 115721-115733, 2023 Nov.
Article in English | MEDLINE | ID: mdl-37889414

ABSTRACT

This research examines the various elements that contribute to the achievement of high-quality economic development (HQED) in China. Specifically, it explores the influence of several major indices, such as the Green Finance Index, Energy Development Index, Higher Education, Technology Market Environment, and Human Capital. In this study, we utilize a Spatial Durbin Model to examine the interdependencies and spatial linkages between various variables, and their combined impact on China's efforts towards achieving HQED. The Green Finance Index serves as an indicator of a nation's dedication to the implementation of financially sustainable practices and investments that align with environmental objectives. The Energy Development Index assesses the extent to which the energy sector contributes to both economic growth and sustainability. The significance of education and skill development in promoting economic advancement is underscored by Higher Education and Human Capital measures. The Technology Market Environment Index examines the impact of the innovation ecosystem on fostering economic growth. The empirical analysis in our study utilizes extensive data sets collected from 30 provinces and regions throughout China. In this study, we analyze the spatial and temporal interactions of the indices, considering the potential spillover effects from adjacent locations. The findings offer significant contributions to understanding the intricate interconnections among green financing, energy development, education, technology, and human capital, and their combined influence on China's continuous endeavor towards achieving high-quality economic growth. Comprehending the intricate interconnections and spatial dynamics holds paramount importance for policymakers and stakeholders who aspire to foster sustainable, inclusive, and ecologically conscientious economic development in China. The results obtained from this study possess the potential to provide valuable insights for evidence-based policy decisions and strategies aimed at promoting the nation's pursuit of HQED objectives.


Subject(s)
Economic Development , Humans , China , Educational Status , Investments
2.
Org Lett ; 22(22): 8758-8763, 2020 Nov 20.
Article in English | MEDLINE | ID: mdl-33151082

ABSTRACT

A meta-dehydrogenative alkylation of arenes with cyclic ethers, ketones, and esters catalyzed by ruthenium is achieved in the presence of a di-tert-butyl peroxide (DTBP) oxidant. Interestingly, when quinoline and isoquinoline are employed as the directing group, or a chain ether as alkylation reagent, the system produces Minisci reaction products. Mechanistic study indicates that meta-dehydrogenative alkylation is a radical process initiated by DTBP with the assistance of a CAr-Ru bond ortho/para-directing effect.

3.
Org Lett ; 22(24): 9450-9455, 2020 Dec 18.
Article in English | MEDLINE | ID: mdl-33232169

ABSTRACT

m-CAr-H bond functionalization of tertiary phosphines was developed using [Ru(p-cymene)Cl2]2 as a catalyst. Desired product structures were confirmed by single-crystal X-ray diffraction. Mechanistic experiments indicated that m-CAr-H bond functionalization was a radical reaction and that a hexagonal ruthenacycle complex was a crucial intermediate in the process. Therefore, this study provides a novel method for the late-stage meta-position modification of biphenyl monophosphine ligands.

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